Room-Temperature Synthesis of Two-Dimensional Hexagonal Boron Nitride Nanosheet-Stabilized CsPbBr3 Perovskite Quantum Dots
2019
Poor stability always restricts the application of all-inorganic perovskite quantum dots (PQDs). Herein, 2D hexagonal boron nitride (h-BN) nanosheets were firstly utilized to stabilize CsPbBr3 PQDs through a facile heterogeneous nucleation–growth process at room temperature. In synthesized h-BN/CsPbBr3 PQD nanocomposites, cubic CsPbBr3 PQDs adhere on h-BN nanosheet surfaces, benefiting from the high specific surface area and abundant mesopores of 2D nanosheets. The nanocomposites prepared at optimized loading of h-BN nanosheets and reaction time display good green-emitting performance with a narrow full width at half maximum of ∼20.0 nm and high color purity of 92.0%. Unique 2D structure and excellent thermal conductivity of h-BN nanosheets endow the h-BN/CsPbBr3 PQD nanocomposites with significantly enhanced humidity stability and thermal stability. The white light-emitting diodes (LEDs) assembled with green-emitting nanocomposites, a blue chip, and a commercial red phosphor possess a low correlated colo...
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