Kinetics of Decomposition of Hydrogen Peroxide in the Presence of Mono- and Heteropolynuclear Complexes of Cu 2+ and Co 2+/3+ with Deprotonated Di- and Triethanolamines

2018 
Features of the decomposition of H2O2 in the presence of polynuclear complexes with Co2Cu2 and Co3Cu2 metal cores with deprotonated and di- and triethanolamines (H2Dea and H3Tea), compounds with the composition (H2Tea)ConCumCl (m + n =1; n = 0.33, 0.5, 0.67), and mononuclear complexes (H2Tea)CuCl and (H2Tea)CoCl were examined. It is suggested that the reaction in the presence of poly- and mononuclear complexes has different mechanisms.
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