Isotope shift and hyperfine splitting of the 4s{yields}5p transition in potassium

2011 
We have investigated the 4s {sup 2}S{sub 1/2}{yields}5p {sup 2}P{sub 1/2} transition (D{sub 1} line) of the potassium isotopes {sup 39}K, {sup 40}K, and {sup 41}K using Doppler-free laser saturation spectroscopy. Our measurements reveal the hyperfine splitting of the 5p {sup 2}P{sub 1/2} state of {sup 40}K, and we have determined the specific mass shift and the nuclear field shift constants for the blue (405 nm) D{sub 1} line.
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