Waterproof leather prepared via polymerization deposition of low-temperature plasmas and preparation method of waterproof leather

The invention discloses waterproof leather prepared via polymerization deposition of low-temperature plasmas and a preparation method of the waterproof leather. The method comprises the following steps: vaporizing siloxane monomers or crylic acid monomers or acrylate monomers or fluorinated acrylate monomers or fluorosilane monomers under the vacuum degree of 25Pa to 45Pa at the temperature of 25 DEG C to 50 DEG C; then adding the vaporized monomers into plasma reaction equipment according to a certain flow and reacting for 1 to 25 minutes under the discharge power within 0.15W/cm to 1.5W/cm ; and depositing the monomers on the leather in the plasma reaction equipment, wherein the thickness of a waterproof membrane deposited on the surface of the leather in a polymerization manner is in a micron level or below the micron level, the static contact angle of the waterproof membrane is within 136 DEG to 155 DEG and the rolling angle of the waterproof membrane is within 7 DEG to 22 DEG, and stagger collagen fibers can be seen clearly by observing through a scanning electron microscope. The method is simple in treatment process, short in time, high in efficiency and low in energy consumption. The obtained waterproof membrane is thin, and not only can maintain the real leather feeling of the surfaces of stone washed leathers, suede leathers, double-purpose leathers and the like but also can maintain the sanitation performance of nature leathers.