Modular Dihydrobenzoazaphosphole Ligands for Suzuki–Miyaura Cross-Coupling
2018
A new family of dihydrobenzoazaphosphosphole ligands was prepared and shown to enable modification of the phosphine electronic character by variation of the N-substituent. This new family of phosphines was shown to be highly active in the Pd-catalyzed Suzuki–Miyaura cross-coupling reaction with hindered coupling partners.
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