Reductive assembly of cyclobutadienyl and diphosphacyclobutadienyl rings at uranium
2013
Despite their prevalence in the d-block, f-block cyclobutadienyl complexes are hitherto unknown. Here, the authors report the syntheses of inverted sandwich cyclobutadienyl dianion uranium(IV) complexes and show computational analysis that suggests the bonding is predominantly electrostatic.
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