Carboxylate-Assisted β‑( Z ) Stereoselective Hydrosilylation of Terminal Alkynes Catalyzed bya Zwitterionic Bis-NHC Rhodium(III) Complex

The zwitterionic compound [Cp*RhCl{(MeIm)2CHCOO}] is an efficient catalyst for the hydrosilylation of terminal alkynes with excellent regio- and stereoselectivity toward the less thermodynamically ...