Material design of negative-tone polyphenol resist for EUV and EB lithography
2007
In order to enable design of a negative-tone polyphenol resist using polarity-change reaction, five resist
compounds (3M6C-MBSA-BLs) with different number of functional group of g-hydroxycarboxyl acid were prepared
and evaluated by EB lithography. The resist using mono-protected compound (3M6C-MBSA-BL1a) showed 40-nm hp
resolution at an improved dose of 52 mC/cm 2 probably due to removal of a non-protected polyphenol while the
sensitivity of the resist using a compound of protected ratio of 1.1 on average with distribution of different protected
ratio was 72 mC/cm 2 . For evaluation of the di-protected compound based resist, a di-protected polyphenol was
synthesized by a newly developed synthetic route of 3-steps reaction, which is well-suited for mass production. The
resist using di-protected compound (3M6C-MBSA-BL2b) also showed 40-nm hp resolution at a dose of 40 mC/cm 2 ,
which was faster than that of mono-protected resist. Fundamental EUV lithographic evaluation of the resist using
3M6C-MBSA-BL2b by an EUV open frame exposure tool (EUVES-7000) gave its estimated optimum sensitivity of 7
mJ/cm 2 and a proof of fine development behavior without any swelling.
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