Microstructure characterization and hydrogen storage properties study of Mg2Ni0.92M0.08 (M = Ti, V, Fe or Si) alloys

Abstract In the present study Mg 2 Ni-type compounds alloyed independently with Ti, V, Fe and Si were successfully prepared by wet-milling followed by sintering. Although these alloyed Mg 2 Ni compounds exhibited a similar hydrogen storage mechanism as that of pure Mg 2 Ni, the dissolution of Ti, V or Fe into the Mg 2 NiH 4 lattice had a considerable catalytic effect on hydrogen desorption from additional MgH 2 . The further structure investigations clearly indicated that the substitution of Ti for Ni could suppress the formation of the micro-twined low-temperature phase (LT2) and promote the formation of the high-temperature phase (HT), thus resulting in remarkably improved hydrogen desorption kinetics for the Mg 2 Ni 0.92 Ti 0.08 –H system.