Preparation method and electroplating method of normal-temperature environment-friendly sulfate trivalent chromium electroplating liquid

2010 
The invention provides a preparation method and an electroplating method of normal-temperature environment-friendly sulfate trivalent chromium electroplating liquid, which relates to electroplating liquid and electroplating technology. The invention solves the problems of poor stability of the traditional trivalent chromium electroplating liquid, low precipitating and depositing rate of harmful gas in an electroplating process, more components of the electroplating liquid, sensitivity for impurities, poor corrosion resistance of an electroplating layer, and the like. The normal-temperature environment-friendly sulfate trivalent chromium electroplating liquid mainly comprises the following components of main salt, a complexation stabilizing agent, a combined additive, a buffering agent and a conducting salt. The electroplating liquid can work at normal temperature, thereby saving energy resources and having simple technology and high deposition rate, wherein the deposition rate can reach above 0.22micron.min under 6A/dm . An anode of the invention is a Ti-based rare-metal tantalum-iridium-titanium anode, the anode oxygen-evolution overpotential is low, and harmful hexavalent chrome can not be generated. The normal-temperature environment-friendly sulfate trivalent chromium electroplating liquid has good corrosion resistance and high stability.
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