Structure of Alloys for (Sm,Zr)(Co,Cu,Fe)z Permanent Magnets: II. Composition, Magnetization Reversal, and Magnetic Hardening of Main Structural Components.

Experimental series of alloys for (Sm,Zr)(Co,Cu,Fe)Z permanent magnets are presented in the concentration ranges that provide wide variations of (4f)/(4d)/(3d) ratios of comprising elements. Optical metallographic analysis, observation of the surface domain structure upon magnetization reversal (Kerr effect), electron microprobe analysis, and measuring the major hysteresis loops of samples at different stages of heat treatment are used to study processes related to the development of the highly coercive state of these samples. It was found that the volume fractions of two main structural components A and B, which comprise 90% of the total sample volume, rigorously control the coercivity at all stages of thermal aging. At the same time, structural components A and B themselves in samples being in the high-coercivity state differ qualitatively and quantitatively in the chemical composition, domain structure and its development in external magnetic fields and, therefore, are characterized by different morphologies of the phases comprising the structural components. Two stages of phase transformations in the sample structure are observed. During isothermal annealing, the cellular structure develops within the B component, whereas, during stepwise (slow) cooling or quenching from the isothermal aging temperature to 400 °C, a phase structure evolves within both the cell boundaries in B and the structural component A. The degree of completion of the phase transformations within micro- and nano-volumes of the components determines the ultimate hysteretic characteristics of the material.