Fast Evaporation Enabled Ultrathin Polymer Coatings on Nanoporous Substrates for Highly Permeable Membranes

Abstract Thin polymer coatings covering on porous substrates are a common composite structure required in numerous applications including membrane separation, and there is a strong need to push the coating thicknesses down to the nanometer scale to maximize the performances. However, producing such ultrathin polymer coatings in a facile and efficient way remains a big challenge. Here, uniform ultrathin polymer covering films (UPCFs) are realized by a facile and general approach based on rapid solvent evaporation. By fast evaporating dilute polymer solutions spread on the surface of porous substrates, we obtain ultrathin coatings (down to ∼30 nm) exclusively on the top surface of porous substrates, forming UPCFs with a block copolymer of polystyrene-block-poly(2-vinyl pyridine) at room temperature or a homopolymer of poly(vinyl alcohol) (PVA) at elevated temperatures. Upon selective swelling of the block copolymer and crosslinking of PVA, we obtain highly permeable membranes delivering ∼2-10 times higher permeance in ultrafiltration and pervaporation than state-of-the-art membranes with comparable selectivities. This work invents a very convenient but highly efficient process for the direct preparation of defective-free ultrathin coatings on porous substrates, which is extremely desired in different fields in addition to membrane separation.