Properties of optically active vacancy clusters in type IIa diamond

In this paper we report on the positron lifetime results obtained for brown and colourless natural diamond. Optical effects of the observed vacancy defects in brown, high pressure, high temperature (HPHT) treated colourless and naturally colourless type IIa diamond samples were studied by combining the positron measurement with monochromatic illumination. Brown diamond was found to contain optically active vacancy clusters (40–60 missing atoms) strongly correlated with the optical absorption spectra. The optical activity of these vacancy clusters is manifested by a photo-excitation induced change of charge from neutral to negative. The clusters gradually disappear during the HPHT treatments, and the samples treated at 2500 °C resemble colourless samples optically and show similar positron lifetimes. The results show that the brown colour originates from the vacancy clusters and that their removal by the HPHT treatment causes the loss of coloration.