Generating singlet oxygen bubbles: a new mechanism for gas-liquid oxidations in water.
2012
Laser-coupled microphotoreactors were developed to bubble singlet oxygen [1O2 (1Δg)] into an aqueous solution containing an oxidizable compound. The reactors consisted of custom-modified SMA fiberoptic receptacles loaded with 150 μm silicon phthalocyanine glass sensitizer particles, where the particles were isolated from direct contact with water by a membrane adhesively bonded to the bottom of each device. A tube fed O2 gas to the reactor chambers. In the presence of O2, singlet oxygen was generated by illuminating the sensitizer particles with 669 nm light from an optical fiber coupled to the top of the reactor. The generated 1O2 was transported through the membrane by the O2 stream and formed bubbles in solution. In solution, singlet oxygen reacted with probe compounds (9,10-anthracene dipropionate dianion, trans-2-methyl-2-pentanoate anion, N-benzoyl-d,l-methionine, or N-acetyl-d,l-methionine) to give oxidized products in two stages. The early stage was rapid and showed that 1O2 transfer occurred via ...
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