SYNTHESIS OF TOLYPOCLADIN AND ISOTOLYPOCLADIN

Walter Werner,Udo Gräfe,W. Ihn,D. Tresselt,Stefan Winter,Erich Paulus

SYNTHESIS OF TOLYPOCLADIN AND ISOTOLYPOCLADIN

1997

Walter Werner
Udo Gräfe
W. Ihn
D. Tresselt
Stefan Winter
Erich Paulus

Abstract Total synthesis of the microbial metabolite tolypocladin ( 1 ) and isomeric isotolypocladin ( 2 ) is described using Friedel-Crafts acylation for condensation of the 2-aza-anthraquinone-(9,10) ring.

Keywords:

Total synthesis
Organic chemistry
Tolypocladin
Acylation
Metabolite
Condensation
Chemistry

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