Enhanced 4.5 V/55 °C cycling performance of LiCoO2 cathode via LiAlO2LiCo1-xAlxO2 double-layer coatings
2019
Abstract Surface structural engineering has been widely applied to improve the electrochemical performances of LiCoO 2 cathodes, especially for applications at high operation voltages (>4.4 V vs. Li) and elevated working temperature (≥50 °C). In this report, Al 2 O 3 layer with an average thickness of 8 nm was firstly obtained on the LiCoO 2 surface, and then was transformed into LiAlO 2 /LiCo 1-x Al x O 2 double-layers by a facile heating treatment. This novel double-layers structure was clearly presented by high resolution transmission electron microscopy (HRTEM) and depth profile of X-ray photoelectron spectroscopy (XPS). Due to the chemical/electrochemical stability of the LiAlO 2 layer and high Li + conductivity of the LiCo 1-x Al x O 2 layer, this cathode with hierarchical structure achieved higher capacity and better cycling stability than the Al 2 O 3 coated LiCoO 2 cathode at both 25 and 55 °C. In addition, this LiAlO 2 /LiCo 1-x Al x O 2 /LiCoO 2 cathode maintained the capacity of 178.1 mA h g −1 (73% capacity retention) after 500 cycles (3.0–4.5 V, 1C), which is very promising to be used in severe operation conditions such as high temperature and voltage.
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