Bifunctional Iron-Amino Complexes: Highly Efficient Catalysts for Dehydrogenation of Ammonia-Borane
2017
Three iron complexes having bidentate 1-(2-aminophenyl)-substituted imidazol-2-ylidene ligands were synthesized by reactions of Cp*FeN(SiMe3)2 (Cp* = η5-C5Me5) with the corresponding imidazolium iodides. These iron complexes exhibited high catalytic performance for dehydrogenation of ammonia-borane in the presence of KN(SiMe3)2. The structure of an active species was determined by its NMR and high resolution mass spectra and also by isolation of its CO adduct.
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