Evolutionof a Strategy for the Enantioselective Synthesisof (−)-Cajanusine
2020
The first enantioselective
synthesis of (−)-cajanusine
is presented. Key features of the route include a rapid synthesis
of the [4.2.0]bicyclooctane core by an enantioselective
isomerization/stereoselective [2+2]-cycloaddition strategy as
well as prominent use of catalytic methods for bond construction.
The evolution of the approach is also presented that highlights unexpected
roadblocks and how novel solutions were developed.
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