Rhodium‐Catalyzed Cyclization of O,ω‐Unsaturated Alkoxyamines: Formation of Oxygen‐Containing Heterocycles
2018
O,ω-Unsaturated N-tosyl alkoxyamines undergo unexpected RhIII -catalyzed intramolecular cyclization by oxyamination to produce oxygen-containing heterocycles. Mechanistic studies show that an aziridine intermediate seems to be responsible for the formation of the heterocycles, possibly via a RhV species.
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