Generation of N-heterocyclic carbenes by metal-mediated coupling of propargylamine and isocyanides.
2005
A new method for the synthesis of heterocyclic carbenes of imidazol-2-ylidene and oxazol-2-ylidene types implying a cycloaddition reaction of propargylamine and propargylic alcohol, respectively, to coordinated isocyanide ligands has been developed.
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