A controlled anion exchange strategy to synthesize core-shell β-bismuth oxide/bismuth sulfide hollow heterostructures with enhanced visible-light photocatalytic activity.

Abstract Heterojunction construction is an exciting direction to pursue for highly active photocatalysts. In this study, novel core/shell β-Bi 2 O 3 /Bi 2 S 3 hollow heterostructures were successfully synthesized through a simple and economical ion exchange method between β-Bi 2 O 3 hollow microspheres and thioacetamide (CH 3 CSNH 2 , TAA), and characterized by multiform techniques, such as XRD, XPS, SEM, TEM, BET, DRS and PL. The results indicated that the core/shell β-Bi 2 O 3 /Bi 2 S 3 hollow heterostructures exhibited strong absorption in visible light region and excellent photocatalytic performance for decomposing rhodamine B (RhB) compared with pure β-Bi 2 O 3 under visible light irradiation. Among the β-Bi 2 O 3 /Bi 2 S 3 photocatalysts with different molar percentage of Bi 2 S 3 to initial β-Bi 2 O 3 , the β-Bi 2 O 3 /Bi 2 S 3 (10%) heterostructures exhibited the highest photocatalytic activity, which was about 3.3 times higher than that of pure β-Bi 2 O 3 sample. Moreover, the study on the mechanism suggested that the enhanced photocatalytic activity mainly resulted from the role of β-Bi 2 O 3 –Bi 2 S 3 heterojunction formed in the β-Bi 2 O 3 /Bi 2 S 3 , which could lead to efficient separation of photoinduced carriers. Additionally, the photosensitization of Bi 2 S 3 and the hollow nature of β-Bi 2 O 3 were also responsible for the high photocatalytic activity.