The 1S0→3,1P1 Transitions In Xe And Kr Atoms Perturbed By CF4 And C2F6

Spectra of Rg 1S0→3,1P1 transitions in Rg/M mixtures, Rg=Xe,Kr, and M=CF4, C2F6, in the Vac UV region have been recorded at higher resolution. Potentials of Rg‐M collisional complexes have been computed using the atom‐bond pairwise additive formalism. Experimental and simulated line shapes of 1S0→3,1P1 transitions are compared and discussed.