General synthesis of β,γ-alkynylglycine derivatives
1990
The coupling of α-haloglycinates 8 with alkynyltin reagents produces the fully protected β,γt-akynylglycines 9. Subsequent deprotection of the amino or carboxyl groups generates differentially protected β,γ-alkynylglycine derivatives 10-14. The free amino acids were found to be too labile to isolate but can be generated in situ and trapped
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