Kinetics of equilibrium attainment between molecular glycolaldehyde structures in an aqueous solution
2000
The kinetics of the isomerization and monomerization of the glycolaldehyde dimer in a D2O solution (pD = 4.3) at 25°C is studied by1H NMR spectroscopy (360 MHz). The dynamics of the concentrations of seven dimeric and two monomeric glycolaldehyde forms present in the solution is examined when the system attains equilibrium. A kinetic scheme of equilibrium attainment in an aqueous solution of glycolaldehyde is proposed. The apparent rate constants of the transformation of the molecular glycolaldehyde structures into each other are determined
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
7
References
15
Citations
NaN
KQI