C1-Symmetric PNP Ligands for Manganese-Catalyzed Enantioselective Hydrogenation of Ketones: Reaction Scope and Enantioinduction Model

Liyao Zeng,Huaxin Yang,Menglong Zhao,Jialin Wen,James H. R. Tucker,Xumu Zhang

C1-Symmetric PNP Ligands for Manganese-Catalyzed Enantioselective Hydrogenation of Ketones: Reaction Scope and Enantioinduction Model

2020

Liyao Zeng
Huaxin Yang
Menglong Zhao
Jialin Wen
James H. R. Tucker
Xumu Zhang

A family of ferrocene-based chiral PNP ligands is reported. These tridentate ligands were successfully applied in Mn-catalyzed asymmetric hydrogenation of ketones, giving high enantioselectivities ...

Keywords:

Ketone
Combinatorial chemistry
Catalysis
Chirality (chemistry)
Enantioselective synthesis
Chemistry
Asymmetric induction
Asymmetric hydrogenation
Ferrocene
Ligand

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