Design of in-situ experimentation for the study of fuel cells with X-rays and neutrons

Abstract In situ neutron and X-ray measurements are of essential importance for the rational design of tailor-made catalysts and cell components, in particular when they can be performed with spatial resolution. Neutron radiography allows the investigation of the local fluid distribution in direct methanol fuel cells (DMFCs) under operating conditions with spatial resolutions in the order of some tens of micrometers. In the through-plane mode, an overview of the local water and gas distribution in the flow field channels is obtained, while the in-plane mode provides information on spatially and time resolved fluid distribution across the cell, hydration/dehydration processes and water distribution across the walls of flow field channels. Combined studies of high resolution neutron radiography and segmented cell measurements are especially valuable, because they enable a correlation of the local fluid distribution and local performance. This knowledge is essential in order to optimise water management and ...