Variable Growth and Characterizations of Monolayer-Protected Gold Nanoparticles Based on Molar Ratio of Gold and Capping Ligands

Controlling the size of nanoscale entities is important because many properties of nanomaterials are directly related to the size of the particles. Gold nanoparticles represent classic materials and are of particular interest due to their potential application in a variety of fields. In this study, hexanethiol-capped gold nanoparticles are synthesized via the Brust-Schiffrin method. Synthesized nanoparticles were characterized by various analytical techniques such as transmission electron microscopy (TEM), scanning tunneling microscopy (STM), UV-Visible absorption spectroscopy (UV-Vis) and electrochemical techniques. We have varied the molar ratio of gold to the protecting agent (hexanethiol) to discover the effect of gold-to-hexanethiol ligand ratio on the size of gold clusters. The clear correlation between cluster size and molar ratio is found that the averaged cluster size decreases from 4.28 ± 0.83 nm to 1.54 ± 0.67 nm as the gold-to-ligand molar ratio changes from 1:1 to 1:9. In contrast to a recent...