Magnetic Neutron Diffraction of Quasi-Two-Dimensional Magnets

This study is devoted to magnetic neutron diffraction analysis (elastic neutron scattering yielding information about spin ordering in magnetic materials). Experimental approaches to magnetism are intensely developed mainly due to the discovery of new functional materials with unusual properties. Nevertheless, magnetic neutron diffraction analysis is a unique method, which makes it possible to directly determine magnetic structures (i.e., values and mutual orientations of magnetic moments and their orientations relative to the crystallographic axes). Neutron diffraction proved to be a good instrument for studying both simple commensurate magnetic structures in bulk samples and more complex noncollinear spiral magnets. Magnetic neutron diffraction is widely applied for studying magnetic structures in nanoscale multilayer film materials. However, bulk samples with a layered crystal structure, which can be considered as natural quasi-two-dimensional objects due to the weakness of interlayer couplings, are of greater interest for physics of low-dimensional magnetism. Our neutron diffraction studies on quasi-two-dimensional magnets, transition-metal oxides A3M2SbO6 (A = Li or Na, M = Co or Ni) and rare-earth intermetallic compounds La1–xTbx(Ni1–xMnx)2Si2, are briefly considered.