Stereoselectivity in intramolecular 1,3-dipolar cycloadditions. Nitrile oxides versus silyl nitronates

Wim Dehaen,Alfred Hassner

Stereoselectivity in intramolecular 1,3-dipolar cycloadditions. Nitrile oxides versus silyl nitronates

1990

Wim Dehaen
Alfred Hassner

Abstract Unlike nitrile oxides, silyl nitronates undergo highly stereoselective intramolecular cycloadditions to produce functionalized carbocyclic or heterocyclic rings.

Keywords:

Nitrone
Bicyclic molecule
1,3-Dipolar cycloaddition
Nitrile
Photochemistry
Silylation
Stereoselectivity
Intramolecular force
Intramolecular reaction
Chemistry
Organic chemistry

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