Rhodium Carbenoid‐Mediated Cyclizations of o‐Alkynyl‐Substituted . alpha.‐Diazoacetophenones.
1993
o-Alkynyl-substituted α-diazoacetophenones undergo facile cyclization to indenone derivatives upon treatment with catalytic quantities of Rh(II) carboxylates. A variety of structural influences were encountered by varying the nature of the substituent group attached to the alkyne carbon atom. The cyclization reaction involves addition of a rhodium stabilized carbenoid onto the acetylenic π-bond to generate a vinyl carbenoid
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