Fabrication and characterization of carbon-coated Li2FeSiO4 nanoparticles reinforced by carbon nanotubes as high performance cathode materials for lithium-ion batteries
2015
Abstract A novel composite consisted of carbon nanotubes (CNTs) and carbon-coated Li 2 FeSiO 4 nanoparticles (Li 2 FeSiO 4 /CNTs/C) has been successfully synthesized by using spray drying technology and carbon chemical vapor deposition method. The Li 2 FeSiO 4 nanoparticles are dispersed homogeneously in CNTs network and assembled as micro-sized porous spherical particles. Such special composite structure constructs an efficient Li + and electron channel, which significantly enhance the Li + diffusion coefficient and reduced the charge transfer resistance, hence may lead to exhibit high specific capacity and excellent rate performances. The Li 2 FeSiO 4 /CNTs/C composite exhibits both high initial discharge capacity and excellent cycling stability (189.2 mA h g −1 at 0.1 C and 71.6 mA h g −1 at 5 C). We believe that adding CNTs and using carbon chemical vapor deposition are effective ways to improve the electrochemical performance of Li 2 FeSiO 4 cathode material.
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