Phototriggered Supramolecular Polymerization of Barbituric Acid Rosette
2017
Supramolecular polymerization of a naphthalene–azobenzene dyad bearing a barbituric acid hydrogen-bonding unit was studied in nonpolar media. The length of supramolecular polymers could be regulated by changing the assembly conditions in terms of kinetics. Supramolecular polymerization initiated by cis-to-trans photoisomerization afforded shorter supramolecular polymers with narrower polydispersity compared to those generated by thermal polymerization.
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