An efficient halogen-free flame retardant for glass-fibre-reinforced poly(butylene terephthalate)

Abstract Compared with poly(butylene terephthalate) (PBT), glass-fibre-reinforced poly(butylene terephthalate) (GF-PBT) is difficult to flame retard with halogen-free flame retardants. In the present study, the aluminium salt of hypophosphorous acid (AP) was used as a flame retardant for GF-PBT. A series of flame-retardant GF-PBT composites was prepared via melt compounding. The flame retardance and combustion behaviour of the composites were studied by limiting oxygen index (LOI), vertical burning test (UL-94) and cone calorimetric test. Thermal behaviours and thermal decomposition kinetics were investigated by thermogravimetric analysis (TGA) under N 2 atmosphere. The addition of AP to the composites could result in an increased LOI value, a UL-94 V-0 (1.6 mm) classification and a better fire performance in cone calorimetric tests. The char morphology observation after flame-retardant tests, calculation of decomposition kinetics, X-ray photoelectron spectroscopy (XPS) and infra-red spectral analysis of the char residue confirmed the condensed-phase flame-retardant mechanism. Furthermore, the mechanical properties of the flame-retardant composites were not deteriorated, retaining an acceptable level.