Rigidly‐Fused Spiro‐Conjugated π‐Systems

Spiro-fused π-systems have gained considerable attention for their application as semiconductors in molecular electronics. Here, a synopsis regarding recent breakthroughs in ladderized spirobifluorenes and indeno-spirobifluorenes, along with further spiro-condensed heteroatomic hydrocarbons with donor-acceptor moieties, is provided. Additionally, an extended range of rigid spirobifluorene polymers and specific doubly linked spiro-systems with partial chiral character is discussed. The diverse applications of the aforementioned structures are thoroughly evaluated.