Pd‐Catalyzed [2 + 2 + 1] Coupling of Alkynes and Arenes: Phenol Diazonium Salts as Mechanistic Trapdoors.

2011 
A wide range of spirocyclic compounds is synthesized by the present new palladium-catalyzed coupling reaction of internal alkynes with 4-phenol diazonium salts.
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