Stereocontrolled Synthesis of Calyculin A: Construction of the C(26)-C( 37) Amide-Oxazole Unit.
1992
(–)-B-[3-(Diisopropylaminodimethylsilyl)allyl]diisopinocampheylborane and Cornforth–Meyers chemistry, and Evans alkylation were employed to construct the C(26)–C(37) amide–oxazole unit of calyculin A.
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