De novo Synthesis of Multisubstituted Aryl Amines Using Alkene Cross Metathesis.

Matthew R. Tatton,Iain Simpson,Timothy J. Donohoe

De novo Synthesis of Multisubstituted Aryl Amines Using Alkene Cross Metathesis.

2014

Matthew R. Tatton
Iain Simpson
Timothy J. Donohoe

Olefin metathesis of allylic alcohols (I) with methyl vinyl ketones (II) in the presence of Zhan-1B catalyst and subsequent Dess-Martin-periodinane oxidation produces generally not-assigned mixtures of unsaturated diones.

Keywords:

Salt metathesis reaction
De novo synthesis
Olefin fiber
Metathesis
Alkene
Allylic rearrangement
Aryl
Chemistry
Catalysis
Organic chemistry
olefin metathesis

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