Gold(I)-catalyzed intramolecular hydroarylation and the subsequent ring enlargement of methylenecyclopropanes to cyclobutenes
2016
The gold(I)-catalyzed intramolecular hydroarylation of methylenecyclopropanes containing aryl propargyl ethers proceeded smoothly to give 2H-chromene derivatives in good to excellent yields under mild conditions. Furthermore, in the presence of IPrAuSbF6, these 2H-chromene derivatives containing a methylenecyclopropane could undergo ring enlargement to give the corresponding cyclobutenes.
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