A unique 6-connected three dimensional cobalt (II) coordination compound: Preparation, structure and magnetic properties
2020
Abstract A new dinuclear Co(II) coordination compound [Co2(DPFE)(oba2−)2]n (1) has been solvothermally synthesized from rigid DPFE ligand and V-shaped polycarboxylate acid H2oba [DPFE = 2,7-di(pyridin-4-yl)-9H-fluorene, H2oba = 4,4′-oxydibenzoic acid]. Compound 1 presents a 2-fold interpenetrated 3D framework containing right-handed helical chains. Magnetic measurements performed on 1 indicate the occurrence of antiferromagnetic interactions among the adjacent Co(II) ions.
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