‘Click’ conjugated porous polymer nanofilm with a large domain size created by a liquid/liquid interfacial protocol

A liquid/liquid interfacial method is used to synthesize a conjugated porous polymer nanofilm with a large domain size. Copper-catalyzed azide–alkyne cycloaddition between a triangular terminal alkyne and azide monomers at a water/dichloromethane interface generates a 1,2,3-triazole-linked polymer nanofilm featuring a large aspect ratio and robustness against heat and pH.