STUDY OF REDUCTION OF TL(I) L-THREONINE COMPLEXES IN AQUEOUS-NONAQUEOUS MEDIA POLAROGRAPHICALLY

The reduction of Tl(I) L-Threonine complexes has been investigated electrochemically in aqueous-nonaqueous medium (60% DMF and 60% Ethanol) and the stability constants of complexes have been evaluated at varying temperatures 308K and 318K. The complexes of Tl(I) with L-Threonine (1:1 and 1:2) have been reported. Values of stability constants have been calculated by using DeFord and Hume's method and the mathematical Mihailov's method has been also applied for comparison the stability constant values. The changes in thermodynamic parameters