Synthesis, Characterization, and Reactivity of Niobium and Tantalum Complexes Bearing Metal−Nitrogen Bonds. X-ray Molecular Structure of [Nb(C 5 H 4 SiMe 3 ){NH(CH 2 ) 2 -η-NH 2 }Cl 3 ] and the Novel Tetranuclear Niobium Oxo Derivative [{Nb(C 5 H 4 SiMe 3 )Cl(μ 2 -O)} 4 (Cl) 2 (μ 3 -O)]