Homoaldol and Aldol Reactions from Common Enolates and Oxiranes: Reaction of Reductively Generated Chromium Enolates through Cationic Rearrangement

Makoto Hojo,Kyosuke Sakata,Xiamuxikamaer Maimaiti,Junya Ueno,Hisashi Nishikori,Akira Hosomi

Homoaldol and Aldol Reactions from Common Enolates and Oxiranes: Reaction of Reductively Generated Chromium Enolates through Cationic Rearrangement

2002

Makoto Hojo
Kyosuke Sakata
Xiamuxikamaer Maimaiti
Junya Ueno
Hisashi Nishikori
Akira Hosomi

Enolates generated from α-bromo esters by the reduction with “Bu6CrLi3” react with oxiranes to afford γ-hydroxy esters and β-hydroxy esters, depending on the Lewis acid used as a promoter.

Keywords:

Cationic polymerization
Lewis acids and bases
Inorganic chemistry
Aldol reaction
Chemistry
Organic chemistry
Chromium

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