Measurement of ClO and CO2 for ACCENT

Observations have shown that ozone in largely removed in rocket plumes within an hour of launch [M.N. Ross, et al., Nature 390, 62-64, 1997]. Large abundances of chlorine oxide (ClO) were first detected in the fresh plume of a Delta rocket in May of 1998 from the NASA WB-57 during the Air Force RISO campaign by the CORE instrument developed at UC Irvine. Similar abundances were detected a month later in the plume of an ATLAS II rocket. Although the maximum ClO observed in these plumes was twenty-five times larger than the highest values ever observed in the perturbed polar vortices, in a new study, [M.N. Ross, et al., Geophys. Res. Lett., 2000, in press] could not account for observed ozone losses based on known chlorine photochemistry. New measurements were obtained in plumes of Delta, Atlas, and Athena rockets in 1999 during ACCENT with the CORE instrument augmented with a modified LiCor non-dispersed infrared detector for fast-response measurements of carbon-dioxide (CO2). The absolute abundance of this specie constrains the rocket emission stoichiometry, and its relative abundance serves as a tracer of dilution. The combination of ClO and CO2 will provide important new insights into the temporal and spatial evolution of reactive chlorine partitioning and its dependence on rocket motor type.