(S)-Dihydrooroxylin A in Human Urine Following Oral Administration of the Traditional Chinese Medicines: Daisaiko-to and Shosaiko-to.
2010
Abstract Dihydrooroxylin A was isolated and characterized from human urine collected after oral administration of traditional Chinese medicines, Daisaiko-to and Shosaiko-to ( Dachaihu-tang and Xiaochaihu-tang in Chinese, respectively). Spectroscopic data (UV, CD, 1 H NMR and MS) and chiral HPLC analysis revealed that this compound had the S -configuration (80% ee). This is the first example of stereoselective hydrogenation of a substituted flavone into its corresponding flavanone in the human body.
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