Solvent-Free Stereoselective Synthesis of (E)-Ethyl-3-Aryl-Acrylates via Wittig Reaction of Arsonium Ylide by Grinding

Chang Qing Wang,Yan Ping Yi,Jia Min Li,Dao An Xiao,Hui Liang,Guang Quan Mei

Solvent-Free Stereoselective Synthesis of (E)-Ethyl-3-Aryl-Acrylates via Wittig Reaction of Arsonium Ylide by Grinding

2013

Chang Qing Wang
Yan Ping Yi
Jia Min Li
Dao An Xiao
Hui Liang
Guang Quan Mei

A solvent-free process for the stereoselective preparation of (E)-ethyl-3-aryl-acrylates by grinding is described. Its advantages are easy workup, mild reaction conditions, high yields, and environmental friendliness.

Keywords:

Ylide
Wittig reaction
Aryl
Solvent
Stereoselectivity
Chemistry
Grinding
Organic chemistry
solvent free
reaction conditions

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