Pd(OAc)2/o‐Chloranil/M(OTf)n: A Catalyst for the Direct C—H Arylation of Polycyclic Aromatic Hydrocarbons with Boryl‐, Silyl‐, and Unfunctionalized Arenes.

Katsuaki Kawasumi,Kenji Mochida,Tomonori Kajino,Yasutomo Segawa,Kenichiro Itami

Pd(OAc)2/o‐Chloranil/M(OTf)n: A Catalyst for the Direct C—H Arylation of Polycyclic Aromatic Hydrocarbons with Boryl‐, Silyl‐, and Unfunctionalized Arenes.

2012

Katsuaki Kawasumi
Kenji Mochida
Tomonori Kajino
Yasutomo Segawa
Kenichiro Itami

The same catalytic system is applied to the reaction of fluoranthene or pyrene with aryl boron compounds, aryl silanes or even unfunctionalized arenes.

Keywords:

Fluoranthene
Boron
Silylation
Medicinal chemistry
Catalysis
O-chloranil
Pyrene
Aryl
Silanes
Chemistry
Organic chemistry

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