An improved methyltrioxorhenium-catalyzed epoxidation of alkenes with hydrogen peroxide
2007
Methyltrioxorhenium (MTO)-catalyzed epoxidation of alkenes with H2O2 has been significantly improved by using 3-methylpyrazole as an additive. A system consisting of 35% H2O2 and MTO–3-methylpyrazole in CH2Cl2 catalyzes the epoxidation of various alkenes in excellent yields. The catalytic activity of MTO–3-methylpyrazole surpasses MTO–pyrazole and MTO–pyridine catalysts. Quantitative yields of epoxides from cyclic and internal alkenes were obtained with only 0.05–0.1 mol% of MTO in the presence of 10 mol% of 3-methylpyrazole.
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