(2,2′-Bipyridine-κ2N,N′)bis(5-thioxo-1,5-dihydro-1,3,4-thiadiazole-3-thiolato-κS)zinc(II)
2007
In the crystal structure of the title compound, [Zn(C2HN2S3)2(C10H8N2)], a twofold rotation axis passes through the Zn atom and the midpoint of the C—C bond linking the two pyridine rings. The ZnII atom is located on a 21 axis and is coordinated by two thiolate S atoms of different 5-thioxo-1,5-dihydro-1,3,4-thiadiazole-3-thiolate ligands and two N atoms of a 2,2′-bipyridine ligand in a tetrahedral geometry, with a Zn—S distance of 2.3204 (8) A and a Zn—N distance of 2.061 (2) A. In addition, mononuclear molecules are linked together to form a one-dimensional chain by N—H⋯S hydrogen bonds.
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
6
References
0
Citations
NaN
KQI