Molecular dissociation in few-cycle laser pulses: From attosecond to femtosecond pulse duration.

The dissociation dynamics of diatomic molecules interacting with (near) optical laser pulses of different duration is investigated by an elaborate discussion of the electric field of the laser and by a direct solution of the time-dependent molecular Schrodinger equation. The systematic variation of the pulse duration from the electronic time scale (attoseconds) to the nuclear time scale (femtoseconds) shows that the employed few-cycle laser pulses lead to well-known but quite different dissociation mechanisms. A comparative calculation with a model pulse and an experimentally realized attosecond pulse emphasizes that, and to what extent, a realistic modeling of the electric field is of central importance in the attosecond regime.